The quenching process of lower bainite
Lower bainite is a microstructure in steel with excellent strength and toughness formed during isothermal transformation. The quenching process for lower bainite (commonly referred to as "lower bainite isothermal quenching") focuses on precisely controlling temperature and time to enable the complete transformation of austenite into lower bainite within the low-temperature range (typically 200~350°C), thereby achieving properties that combine high strength, high hardness, and good toughness. Here is a detailed description of the process and related key points:
The formation of lower bainite relies on an isothermal transformation mechanism: the steel is heated to the austenitizing temperature and held to obtain a uniform austenitic structure. It is then rapidly cooled to the temperature range for lower bainite transformation (avoiding the transformation zones of pearlite and upper bainite) and held at this temperature for a sufficient time to allow complete transformation of austenite into lower bainite, followed by air cooling to room temperature.
Compared with martensitic quenching (rapid cooling below the Ms point to obtain martensite), lower bainite quenching avoids the brittleness of martensite through "isothermal transformation" while retaining high strength. This is because lower bainite consists of extremely fine ferrite laths and uniformly distributed carbides, with a much smaller interlamellar spacing than upper bainite, and the carbides are granular rather than lamellar, resulting in a better balance of strength and toughness.
- Purpose: To fully dissolve carbides in the steel and obtain a uniform, fine austenitic structure, laying the foundation for subsequent transformation.
- Process Parameters:
- Austenitizing Temperature: Determined by the steel composition, generally 30~50°C above Ac3 (for hypoeutectoid steels) or between Ac1 and Ac3 (for hypereutectoid steels, to avoid network carbides). For example:
- Medium carbon steels (e.g., 45 steel): 820~860°C;
- Medium carbon low-alloy steels (e.g., 40Cr): 840~880°C;
- High carbon steels (e.g., T8 steel): 780~820°C (to prevent coarse grains from overheating).
- Holding Time: Determined by the workpiece thickness and loading capacity to ensure austenite homogenization. Typically 1~3 hours (shorter for small workpieces, up to 30 minutes; longer for large workpieces), avoiding underheating (incomplete austenitization) or overheating (coarse grains, leading to reduced performance).
- Purpose: To rapidly cool the austenitized workpiece to the lower bainite transformation temperature range (200~350°C), preventing premature transformation in the pearlite (500~600°C) or upper bainite (350~500°C) zones, ensuring "directional" transformation of austenite into lower bainite.
- Process Parameters:
- Cooling Medium: Must provide sufficient cooling rate (exceeding the steel's critical cooling rate). Common media include:
- Molten salts (e.g., nitrate-nitrite baths, with low melting points and easy temperature control);
- Mineral oils (suitable for small workpieces, with slightly slower cooling than molten salts);
- Polymer solutions (e.g., polyvinyl alcohol solutions, with adjustable cooling capacity).
- Cooling Endpoint: Rapidly cool the workpiece to 200~350°C (specific temperature determined by the steel's TTT curve; e.g., 250~300°C for low-alloy steels).
- Purpose: Hold at the set low temperature to fully transform austenite into lower bainite (minimizing retained austenite).
- Process Parameters:
- Isothermal Temperature: Usually 200~350°C (characteristic range for lower bainite). Lower temperatures produce finer lower bainite laths, increasing strength and hardness but slowing transformation (requiring longer holding); higher temperatures (near 350°C) may form partial upper bainite, reducing toughness.
- Isothermal Time: Determined by the steel's TTT curve to ensure complete austenite transformation. Examples:
- 40Cr steel at 280°C: ~2~4 hours;
- 60Si2Mn spring steel at 250°C: ~3~5 hours.
- Judgment Criteria: Microstructural inspection (lower bainite appears as dark needle-like/lamellar structures without pearlite or martensite) or empirical formulas (e.g., extend time by 0.5~1 hour per 10mm thickness).
- After isothermal holding, the workpiece can be air-cooled to room temperature (no need for continued rapid cooling). Austenite has already fully transformed into lower bainite, so air cooling avoids martensite formation or other adverse structures and prevents stress cracking from excessive cooling rates.
Lower bainite quenching is applicable to medium-carbon and medium-carbon low-alloy steels (with good hardenability for isothermal transformation), including:
- Medium carbon steels: 45, 50, etc.;
- Medium carbon low-alloy steels: 40Cr, 42CrMo, 35CrMo, etc.;
- Spring steels: 60Si2Mn, 50CrVA, etc.;
- Bearing steels: GCr15 (control austenitizing temperature to avoid coarse grains).
Reason: These steels contain Cr, Mn, Mo, etc., which slow pearlite transformation (delaying the TTT curve "nose"), extend austenite stability in the low-temperature zone, and facilitate lower bainite formation. Low-carbon or high-alloy steels (e.g., austenitic stainless steels) are unsuitable due to mismatched transformation kinetics.
- Performance Advantages: Lower bainite has a hardness of HRC45~55 (close to martensite) but 2~3 times higher impact toughness (αk) than martensite (e.g., 40Cr after lower bainite quenching has αk≥80J/cm² vs. 30~50J/cm² for martensitic quenching), with excellent fatigue strength and wear resistance.
- Applications: Parts requiring "strength-toughness balance," such as gears, drive shafts, connecting rods, springs, and bearing rings.
- Austenitization Control: Excessively high temperatures cause coarse austenite grains and roughened lower bainite, reducing toughness; low temperatures lead to incomplete austenitization, with residual carbides impairing transformation uniformity.
- Cooling Rate: Must rapidly pass through the pearlite zone (500~600°C); otherwise, pearlite forms, drastically reducing strength (select media with appropriate cooling capacity, e.g., molten salt baths, to ensure rates exceed critical values).
- Isothermal Parameters: Strictly follow TTT curves for temperature and time—deviations cause excessive retained austenite (reduced hardness) or partial upper bainite (reduced toughness).
- Workpiece Geometry: For large or complex parts, control heating/cooling rates to avoid stress cracking (use stepped heating or pre-cooling to higher temperatures before isothermal holding).
This process achieves an excellent strength-toughness balance, making it a critical alternative to traditional martensitic quenching (for hardness-focused applications) in machinery and automotive industries.